Use this workbook alongside the course. Read each module, study the visual, write your reflections, and complete the self-check. Draft content prepared to the cited standards — not legal advice.
Module 1
OSHA, Your Rights, and the Employer's Duty
§ OSH Act of 1970 §5; 29 CFR 1903/1904
Learning objectives
→ Explain the purpose of OSHA and the employer's obligation under the General Duty Clause (§5(a)(1)).
→ Identify the core worker rights guaranteed under the OSH Act, including training, hazard information, and records access.
→ Recognize when and how to file a complaint or request an inspection without fear of retaliation.
→ Describe the employer's recording and reporting duties under 29 CFR 1904.
The Occupational Safety and Health Act of 1970 created OSHA to assure safe and healthful working conditions. Under the General Duty Clause (§5(a)(1)), every employer must furnish a workplace free from recognized hazards likely to cause death or serious harm, and under §5(b) employees must comply with the safety and health standards that apply to their own conduct. The General Duty Clause fills the gaps where no specific standard exists — for example, an employer who knows that an unguarded floor opening is likely to cause a fall has a duty to address it even without a citation-by-number.
You have the right to: training in a language and vocabulary you understand, information about the hazards you work with (container labels and Safety Data Sheets), access to your own exposure monitoring and medical records, and the ability to file a complaint or request an OSHA inspection. Critically, you can exercise these rights without retaliation — an employer may not fire, demote, or otherwise punish you for raising a safety concern. If you believe you were retaliated against, you can file a whistleblower complaint with OSHA, generally within 30 days.
Employers must record serious work-related injuries and illnesses on the OSHA 300 log (29 CFR 1904) and post the annual summary where workers can see it. They must also report any work-related fatality to OSHA within 8 hours, and any inpatient hospitalization, amputation, or loss of an eye within 24 hours. This program documents your training and completion as part of that broader safety and recordkeeping system.
Your rights
✓Training in a language you understand
✓Hazard info — labels and Safety Data Sheets
✓Access to your exposure & medical records
✓File a complaint or request an inspection — free from retaliation
Employer's duties
✕Furnish a workplace free of recognized serious hazards
✕Record injuries/illnesses on the OSHA 300 log
✕Report a fatality within 8 hours
✕Report hospitalization, amputation, or eye loss within 24 hours
The OSH Act is a two-way street: worker rights paired with employer duties.
Key takeaways
✓ Employers must furnish a workplace free of recognized serious hazards, and workers must follow safety rules.
✓ You have enforceable rights to training you understand, hazard information, and your own exposure and medical records.
✓ Reporting a hazard or filing a complaint is legally protected — retaliation is prohibited.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. Under the General Duty Clause, the employer must:
A. Provide a workplace free of recognized serious hazards
B. Only follow rules that are convenient
C. Train workers only if they ask
2. You can file an OSHA complaint and be protected from:
A. Overtime
B. Retaliation
C. Taxes
3. Where does an employer record serious work-related injuries and illnesses?
A. The Safety Data Sheet
B. The OSHA 300 log under 29 CFR 1904
C. The employee handbook
4. A work-related fatality must be reported to OSHA within:
A. 8 hours
B. 30 days
C. One year
Module 2
The Right to Know & the Written Program
§ 1910.1200(e),(h)
Learning objectives
→ Explain the purpose of the Hazard Communication Standard as a worker "Right to Know" rule.
→ Identify the required components of a written hazard communication program.
→ Locate the workplace chemical inventory and the Safety Data Sheets that support it.
→ Recognize when training must be delivered or refreshed for a new chemical hazard.
The Hazard Communication Standard — often called the "Right to Know" law — exists to make sure you are informed about the hazardous chemicals you handle or work near. The premise is simple: chemical manufacturers and importers classify the hazards of what they produce and pass that information downstream through labels and Safety Data Sheets, and your employer translates it into something usable on the floor. You have the right to know what chemicals are present, what they can do to you, and how to protect yourself.
To put that right into practice, your employer must maintain a written hazard communication program that describes how labeling, Safety Data Sheets, and training are handled at your site. That written program is paired with a list (or inventory) of the hazardous chemicals known to be present — for example, the degreasers in the parts-washing bay, the propane for the forklifts, and the cleaning chemicals in the janitor closet. Containers must be labeled, Safety Data Sheets must be readily accessible during your shift, and the program itself must be available to you on request.
Training is the part you experience directly. It must be provided at your initial assignment and again whenever a new chemical hazard is introduced to your work area — not on a fixed calendar, but whenever the hazard picture actually changes. If your team starts using a new solvent next month, you are entitled to be trained on it before you are expected to work with it, including how to read its label and where to find its SDS.
✓A written hazard communication program available on request
✓A list (inventory) of the hazardous chemicals present
✓Labels on all containers
✓Safety Data Sheets readily accessible during your shift
✓Employee training at assignment and when a new hazard appears
What your employer's written HazCom program must include
Key takeaways
✓ HazCom is a "Right to Know" rule: hazard information flows from manufacturers to you through labels and Safety Data Sheets.
✓ Employers must keep a written program, a chemical inventory, labeled containers, and accessible SDSs.
✓ Training happens at initial assignment and again whenever a new chemical hazard enters your work area.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. Training on a new chemical hazard must occur:
A. Once a decade
B. When the new hazard is introduced to your work area
C. Never
2. The written hazard communication program must describe how the employer handles:
A. Only fire drills
B. Labeling, Safety Data Sheets, and employee training
C. Payroll and scheduling
3. A list (inventory) of the hazardous chemicals present in the workplace must be:
A. Kept secret from employees
B. Maintained by the employer and available to workers
C. Submitted to OSHA before any chemical is used
Module 3
GHS Labels & Pictograms
§ 1910.1200(f); App C (2024 final rule, GHS Rev 7)
Learning objectives
→ Identify the six required elements of a GHS-aligned container label.
→ Distinguish the signal words "Danger" and "Warning" by severity.
→ Recognize the standard GHS pictograms and the hazard class each one signals.
→ Describe proper labeling of workplace and secondary containers, including when one may stay unlabeled.
OSHA updated the Hazard Communication Standard in 2024 (final rule effective July 19, 2024) to better align it with GHS Revision 7. Employers retrain on the updated labels and Safety Data Sheets within the rule's compliance window — substances by July 20, 2026, and mixtures by July 19, 2028 — but the core label format you already use stays the same. The 2024 update added practical clarity for small packaging, "released for shipment" labeling, and the hazards of combustible dusts.
Under GHS, every label on a shipped container of hazardous chemical carries six elements: a product identifier (the chemical name or code that matches the SDS), a signal word, hazard statements, pictograms, precautionary statements, and supplier information. There are two signal words and only one appears on a given label: "Danger" flags the more severe hazards, while "Warning" flags the less severe. A bottle of strong acid might read "Danger" with the corrosion pictogram and the hazard statement "Causes severe skin burns and eye damage," followed by precautionary statements such as "Wear protective gloves and eye protection."
The pictograms are the fastest part of the label to read: each is a black symbol inside a red diamond border. Common ones include the flame (flammables), the skull-and-crossbones (acute toxicity), the health hazard "person" symbol (carcinogens, respiratory sensitizers), corrosion (skin/eye damage and metal corrosion), the exploding bomb, the gas cylinder, the flame-over-circle (oxidizers), the environmental fish-and-tree, and the exclamation mark (irritants, less severe hazards). Learn to read the signal word and pictograms at a glance — they tell you the severity and type of hazard before you ever touch the chemical. Containers you fill on the job (workplace or secondary containers) still need to be marked, the one narrow exception being a portable container meant for the immediate use of the single worker who filled it. Never use a chemical from an unlabeled container.
1Product identifier
→
2Signal word
→
3Hazard statements
→
4Pictograms
→
5Precautionary statements
→
6Supplier information
The six required elements on a GHS-aligned shipped label
Key takeaways
✓ A shipped GHS label has six elements: product identifier, signal word, hazard statements, pictograms, precautionary statements, and supplier information.
✓ "Danger" signals a more severe hazard than "Warning," and pictograms are black symbols in a red diamond border that flag the hazard type.
✓ Workplace and secondary containers must be labeled; never use a chemical from an unlabeled container.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. The GHS signal word indicating the MORE severe hazard is:
A. Caution
B. Warning
C. Danger
2. You should use a chemical from an unlabeled container:
A. Yes, if you think you know it
B. Never
C. Only on Fridays
3. How many elements are required on a GHS-aligned shipped container label?
A. Three
B. Six
C. Sixteen
4. GHS pictograms are displayed as:
A. A black symbol inside a red diamond border
B. A blue circle with white text
C. A plain yellow triangle with no symbol
Module 4
Safety Data Sheets (the 16 Sections)
§ 1910.1200(g); App D
Learning objectives
→ Describe the standardized 16-section SDS format and why a fixed order matters.
→ Navigate quickly to the right SDS section during an emergency.
→ Use Section 8 to determine exposure limits and required PPE for daily work.
→ Explain employees' right to readily accessible Safety Data Sheets during their shift.
Every hazardous chemical in your workplace comes with a Safety Data Sheet (SDS) prepared by the manufacturer or importer. The value of the SDS is its consistency: GHS sets a standardized 16-section format and a fixed order, so the same information lives in the same place on every sheet — whether it covers a solvent, a paint, or a compressed gas. The sections are: 1 Identification, 2 Hazard(s) identification, 3 Composition/information on ingredients, 4 First-aid measures, 5 Fire-fighting measures, 6 Accidental release measures, 7 Handling and storage, 8 Exposure controls/personal protection, 9 Physical and chemical properties, 10 Stability and reactivity, 11 Toxicological information, and Sections 12–15 (ecological, disposal, transport, and regulatory information, whose enforcement falls largely to other agencies), plus 16 Other information, including the SDS revision date.
Because the order never changes, you can navigate an SDS under pressure. In an emergency, go straight to Section 4 for first aid — for instance, whether to flush eyes for 15 minutes or induce vomiting — and Section 6 for how to contain and clean up a spill. If a coworker is splashed with a corrosive, you should be able to reach Section 4 without reading the whole sheet.
For routine work, Section 8 is the one you will use most: it lists exposure limits (such as OSHA permissible exposure limits and other recommended limits) and the engineering controls and personal protective equipment appropriate for the chemical — the gloves, eye protection, or respirator the manufacturer recommends. Sections 2 and 9 round out the picture with the hazard classification and physical properties like flash point. SDSs must be readily accessible to you during every shift, whether that means a binder in the work area or an electronic system you can reach without barriers such as a password you do not have or a locked office.
12 — Hazard identification
→
24 — First-aid measures
→
36 — Accidental release
→
48 — Exposure controls / PPE
→
59 — Physical & chemical properties
The sections you reach for most often in the 16-section SDS
Key takeaways
✓ Every SDS follows the same 16-section format in a fixed order, so information is always in a predictable place.
✓ In an emergency go to Section 4 (first aid) and Section 6 (spill response); for daily work use Section 8 for exposure limits and PPE.
✓ SDSs must be readily accessible to employees during every shift, on paper or electronically without barriers.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. For required PPE and exposure limits, read SDS Section:
A. Section 1
B. Section 8
C. Section 16
2. How many standardized sections does a GHS Safety Data Sheet contain?
A. 6
B. 9
C. 16
3. A coworker splashes a corrosive in their eyes. Which SDS section gives the first-aid response?
A. Section 4
B. Section 9
C. Section 15
4. Safety Data Sheets must be:
A. Mailed to OSHA monthly
B. Readily accessible to employees during their shift
C. Kept only at the corporate headquarters
Module 5
Personal Protective Equipment (PPE) Fundamentals
§ 29 CFR 1910.132–.138
Learning objectives
→ Describe the employer's duty to assess hazards, provide PPE, and train workers under 1910.132.
→ Match PPE categories — eye, head, hearing, respiratory, hand, foot, and body protection — to their hazards.
→ Explain why correct fit and proper selection determine whether PPE actually protects.
→ Inspect PPE before use and remove damaged equipment from service.
Under 29 CFR 1910.132, employers must assess the workplace to determine what PPE is needed, provide it (in most cases at no cost to the worker), and train each worker on what PPE is necessary, when and how to wear it, its limitations, and proper care, maintenance, useful life, and disposal. The hazard assessment must be documented through a written certification identifying the workplace evaluated and the person who performed it.
Categories track the body part or exposure they address: eye and face protection (1910.133), head protection (1910.135), hearing protection, respiratory protection (1910.134), hand protection with the glove material matched to the chemical or mechanical hazard (1910.138), foot protection (1910.136), and full-body protection. The wrong choice creates a false sense of safety — a nitrile glove may resist one chemical while dissolving in another, and a respirator that does not seal to the face offers little protection.
PPE only works when it fits and is worn correctly for the specific hazard. Inspect PPE before each use and remove damaged equipment from service rather than risking a failure mid-task. NOTE: hands-on fit and skills components (for example, respirator fit testing under 1910.134) are completed in person with your employer; this module covers the knowledge foundation, not the physical fit test.
✓Eye & face protection — impact, splash, and optical hazards (.133)
✓Head protection — falling objects and bump hazards (.135)
✓Hearing protection — high noise exposure
✓Respiratory protection — airborne contaminants; requires fit (.134)
✓Hand protection — glove material matched to the hazard (.138)
✓Foot protection — crush, puncture, and electrical hazards (.136)
PPE categories matched to the body part or exposure they protect (29 CFR 1910.133–.138).
Key takeaways
✓ Employers must assess the workplace, provide required PPE (usually at no cost), and train each worker on its use.
✓ PPE only works when it fits and is matched to the specific hazard — the wrong glove or a poor respirator seal is dangerous.
✓ Inspect PPE before every use and take damaged equipment out of service immediately.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. PPE training must cover all EXCEPT:
A. When and how to wear it
B. Its limitations
C. The price your employer paid
2. Who is responsible for assessing the workplace to determine required PPE?
A. The employer
B. Each individual worker
C. OSHA inspectors
3. Before each use, PPE should be:
A. Inspected, with damaged items removed from service
B. Worn regardless of condition
C. Shared between workers without checking
Module 6
Protective Measures & Your Workplace
§ 1910.1200(h)(3)
Learning objectives
→ Identify the operations in your work area where hazardous chemicals are present.
→ Apply the hierarchy of controls to reduce chemical exposure.
→ Detect a chemical release using monitoring, odor, and visual cues.
→ Respond to spills, leaks, and exposures and report them promptly.
Labels and SDSs tell you about a chemical in general; this part of training makes it specific to where you actually work. Your training must cover the operations in your work area where hazardous chemicals are present — the spray booth, the battery-charging station, the parts washer — and the protective measures in place for each. That includes engineering controls (such as local exhaust ventilation that pulls vapors away from your breathing zone), safe work practices, personal protective equipment, and the permissible exposure limits that define how much exposure is allowed.
Think in terms of the hierarchy of controls: it is always better to eliminate or substitute a hazard, then engineer it out, then control it with work practices, before relying on PPE as the last line of defense. PPE matters, but a respirator or a pair of nitrile gloves only works when it is the right type, fits, and is worn correctly — so use the PPE specified on the SDS (Section 8) and by your employer, and inspect it before each use.
You also need to recognize when something has gone wrong. A release may show up through monitoring equipment and alarms, through odor, or through visual signs such as a puddle, a stain, fumes, or a hissing container. Do not wait to be certain: if you see, smell, or suspect a leak, spill, or exposure, follow your site's procedures and report it immediately so it can be contained before someone is hurt. Knowing the location of eyewash stations, safety showers, and spill kits before you need them is part of being ready.
Elimination — remove the hazard
Substitution — replace with a safer chemical
Engineering controls — e.g. local exhaust ventilation
Safe work practices
PPE — last line of defense
most preferred ↑ · last resort ↓
Hierarchy of controls — most effective at top, PPE last
Key takeaways
✓ HazCom training is workplace-specific: it covers the chemicals, operations, and protective measures in your actual work area.
✓ Follow the hierarchy of controls and treat PPE as the last line of defense, using exactly what the SDS and employer specify.
✓ Detect releases by monitoring, odor, and visual signs, and report spills, leaks, and exposures immediately.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. HazCom training must be specific to:
A. Generic chemicals only
B. The chemicals and operations in YOUR work area
C. No particular workplace
2. In the hierarchy of controls, personal protective equipment is:
A. The first and best control to rely on
B. The last line of defense, after elimination and engineering controls
C. Never necessary if a chemical is labeled
3. Which of these is a sign that a chemical release may be occurring?
A. An unusual odor, fumes, or a puddle near a container
B. A clean, organized workbench
C. A properly closed and labeled drum
Module 7
Final Assessment
§ 1910.1200
Learning objectives
→ Demonstrate mastery of the Right to Know program, GHS labels, and Safety Data Sheets.
→ Apply HazCom knowledge to realistic workplace label, SDS, and response scenarios.
→ Confirm readiness to work safely around hazardous chemicals before certification.
This final assessment is a comprehensive check across the whole course: the Right to Know written program, GHS label elements and pictograms, the 16-section Safety Data Sheet, and the workplace-specific protective measures that keep you safe.
Answer based on what you learned in the lessons rather than memory of a single fact. A passing score plus identity verification is required to complete the course and have your training documented. If you are unsure of any topic, revisit the relevant module before continuing.
Key takeaways
✓ HazCom ties together a written program, GHS labels and pictograms, Safety Data Sheets, and workplace-specific protections.
✓ A passing score and verification are required to complete the course and document your training.
Reflect
In your own words, what is the most important thing from this module, and how does it apply to you?
Check your understanding
1. The "Right to Know" standard is:
A. 1926 Subpart M
B. 1910.1200 Hazard Communication
C. 1910.1030
2. On a GHS label, "Danger" compared to "Warning" indicates:
A. A less severe hazard
B. A more severe hazard
C. The same severity
3. To find the required PPE and exposure limits for a chemical, you read SDS:
A. Section 8
B. Section 12
C. Section 16
4. You find a spray bottle filled with an unknown chemical and no label. You should:
A. Use it if it smells familiar
B. Not use it and report it so it can be identified and labeled
C. Pour it down the drain immediately
Answer key
OSHA, Your Rights, and the Employer's Duty:1-A, 2-B, 3-B, 4-A
The Right to Know & the Written Program:1-B, 2-B, 3-B
GHS Labels & Pictograms:1-C, 2-B, 3-B, 4-A
Safety Data Sheets (the 16 Sections):1-B, 2-C, 3-A, 4-B
Personal Protective Equipment (PPE) Fundamentals:1-C, 2-A, 3-A
Protective Measures & Your Workplace:1-B, 2-B, 3-A
Final Assessment:1-B, 2-B, 3-A, 4-B
Certa · Participant Workbook · Hazard Communication (HazCom / GHS). Draft content prepared to the cited standards; verify against the authority before relying on it.